1) Make sure "Google Chrome" process is down.
2) Open "Terminal" (Application/Utilities) application.
3) Below listed samples to run in normal mode:
open -a "Google Chrome" --args --proxy-server="https://za133.nordvpn.com:89"
And for private mode use:
open -a "Google Chrome" --args -incognito --proxy-server="https://za133.nordvpn.com:89"
It's just example, use real servers you need in.